… used to design and synthesize novel crystalline molecule-based materials exhibiting useful
… molecular magnetic materials [19,20]. The focus of this review is on transition-metal SMMs …

… Unexpectedly, the magnetic moment of the transition metal … The present study opens a
way toward the rational design of … N 2 molecule boosts the activation of the N 2 molecule and …

… This work provides new insights into the rational design of NRR catalysts and explores … is
that the transition metal atom has both occupied and empty d orbitals and the N 2 molecule has …

… and chemical functionality of the molecular building blocks, … of inorganic TIs such as
transition-metal dichalcogenides. (88) … be engineered to realize different magnetic phases (106) or …

… It is prevalent to design magnetic MOFs by introducing the … and magnetic behavior of metal
phthalocyanine (Pc)-based 2D … Besides the 3d transition metal centers, the implementation …

… Benefiting from the well-defined structure, iron phthalocyanine (FePc) is … This work provides
guidance for the design of efficient … ] According to molecular-orbital analysis, the orbital …

… of several molecular magnets, rapid growth of SMM-based … (24−28) Amid d-block metal
complexes, 4d and 5d series … highest magnetic anisotropy among first-row transition metal-based …

… The combination of transition metal (TM) atoms and high electron affinity … 5d–f. As the reaction
progresses, the N–N bond length increases linearly, indicating that the inert N 2 molecules …

… This work will shed some light on the rational design of … ], which consists of TM (3d/4d/5d)
as active sites and TCNEs as … From Figure 1b, we can see that all of the TCNE molecules are …

… challenges by implementing molecules in the design of such … be overcome in order to switch
the magnetization direction. … : (1) the 3 d series of transition metal elements corresponds to a …