… used to design and synthesize novel crystalline molecule-based materials exhibiting useful
… molecular magnetic materials [19,20]. The focus of this review is on transition-metal SMMs …

… This work will shed some light on the rational design of … ], which consists of TM (3d/4d/5d)
as active sites and TCNEs as … From Figure 1b, we can see that all of the TCNE molecules are …

… as urea, is an organic molecule formed by the simultaneous … site, providing inspiration for the
design of highly selective and … of extended phthalocyanine is transition metal 3d, 4d, 5d (TM …

… and dd transitions of transition metal show relatively weak … provides a new way to design
CPL-emitting molecules, that is … stack between two phthalocyanine subunits was induced by …

… for designing new spintronic/magnetic devices [14,15]. … a 3d 10 4s 1 , 4d 10 5s 1 , and 5d
10 6s 1 electronic configuration, … charge transfer able to “switch off” the CoTPP magnetization …

… , as well as some heterometallic 3d–4d/5d and 3d–4f complexes [61]… is much larger than that
for transition metal systems. (ii) The … The modification of the parent phthalocyanine ligand by …

… design and synthesis of low-dimensional molecular magnets… giant transition metal spin-systems
providing massive magnetic … seems to switch the parity from non-Kramers to Kramers. …

… single-ion magnet (SIM)/SMMs with 4d and 5d transition metal, … (a) The structure of the
phthalocyanine molecule, and (b) … One of the imposing challenges in this field is to design and …

… It is prevalent to design magnetic MOFs by introducing the … and magnetic behavior of metal
phthalocyanine (Pc)-based 2D … Besides the 3d transition metal centers, the implementation …

… the design and preparation of lanthanide-based complexes … such as porphyrins or
phthalocyanines are highly chemically … coordination chemistry of transition metal ions and …